Titanium & Advanced Metals

Category

  • Bar and Rod

  • Plate and Sheet

  • Strip

  • Pipe and Tube

  • Wire

  • Welding

  • Powder Material

  • Cast Products

  • Forged Products

  • Fittings

  • Fastening

    Forms & Sizes

    Round Bar:
    φ2–500 mm, 1–6 m length

    Flat/Square Bar:
    4–100 mm thickness/width

    Hex Bar:
    A/F 3–100 mm

    Hollow Bar:
    OD 20–300 mm

    Forms & Sizes

    Sheet:
    0.3–6 mm thickness

    Medium Plate:
    6–25 mm thickness

    Heavy Plate:
    25–100 mm thickness

    Forms & Sizes

    Standard Strip:
    0.05–3 mm thick,
    10–600 mm wide

    Precision strip:
    0.01–0.5 mm thick,
    tight tolerance ±0.005 mm

    Foil:
    0.005–0.1 mm thick

    Forms & Sizes

    Seamless Tube:
    OD 6–450 mm,
    WT 1–50 mm,
    1–12 m length

    Welded Tube:
    OD 10–600 mm,
    WT 1–20 mm

    Capillary Tube:
    OD 1–10 mm,
    WT 0.1–2 mm

    Forms & Sizes

    Wire Form:
    Cold Drawn Wire,
    Bright Wire,
    Spring Wire,
    Fine Wire,
    Ultra-fine Wire

    General Diameter:
    φ0.1–10 mm

    Coil Weight:
    50–500 kg,
    customizable tolerance

    Forms & Sizes

    Solid Wire:
    φ0.8–4.0 mm

    Flux-cored Wire:
    φ1.2–4.0 mm

    Welding Rod:
    φ2.0–5.0 mm

    Forms & Sizes

    Powder Form:
    AM 3D Printing Powder,
    Spherical Powder,
    Gas-atomized Powder,
    Water-atomized Powder

    Particle Size:
    10–150 μm

    Sphericity:
    ≥90% for AM grade

    Forms & Sizes

    Cast Ingot:
    φ200–800 mm

    Precision Casting:
    min wall 0.5 mm

    Cast Pipe:
    OD 100–600 mm,
    WT 10–50 mm

    Forms & Sizes

    Forged Bar:
    Φ35–500 mm

    Forged Ring:
    OD 200–2000 mm

    Forging Weight:
    1–5000 kg

    Forms & Sizes

    Fittings Form:
    Elbow, Tee, Reducer, Flange, Cap, Outlet, Lap Joint

    Size range:
    1/2''–24'' (DN15–DN600)

    Wall thickness:
    Sch10–Sch160, STD, XS, XXS

    Pressure Class:
    150–2500 LB

    Forms & Sizes

    Fastening Form:
    Bolt, Nut, Screw, Stud, Washer, Pin, Rivet

    Metric: M3–M64

    Imperial: #4–2.5''

    Length: 6–500 mm

R04295 Product Description

Overview

R04295 is the niobium-hafnium-titanium alloy C-103, containing nominally 10% hafnium and 1% titanium. This datasheet presents the material within the American (ASTM / ASME / UNS) standard system.

Developed during the 1960s space programme, C-103 (Nb-10Hf-1Ti) is the dominant niobium alloy for aerospace and propulsion. The hafnium and titanium additions give a strong, formable, weldable alloy that retains useful strength to very high temperature (service to about 1480 °C) while keeping the relatively low density and excellent fabricability of niobium. Like all refractory metals it oxidises in air at elevated temperature and requires a protective coating or inert/vacuum service. It is supplied in the annealed condition.

Typical applications include rocket-nozzle extensions, thrust chambers, spacecraft and propulsion components, hypersonic-vehicle structures, and other high-temperature aerospace hardware.

1. Physical Properties

Property Value Unit
Density 8.85 g/cm³
Melting point ~2350 °C
Elastic modulus 105 GPa
Coefficient of thermal expansion (20–100 °C) 7.3 µm/m·°C
Thermal conductivity (20 °C) 53.7 W/m·K
Specific heat (20 °C) 265 J/kg·K
Structure Body-centred cubic (BCC)

2. Chemical Composition (wt %)

Element Symbol Min % Max % Role in Alloy
Niobium Nb Balance Base element (~89%)
Hafnium Hf 9.0 11.0 Strength, oxidation resistance
Titanium Ti 0.7 1.3 Strength, mechanical properties
Zirconium Zr 0.7 Residual / minor
Tantalum Ta 0.5 Residual
Tungsten W 0.5 Residual
Oxygen O 0.015 Interstitial impurity
Carbon C 0.015 Interstitial impurity

3. Mechanical Properties

Annealed condition, typical values for ASTM B654 / AMS 7852 R04295 (C-103).

Condition Property Value
Annealed Tensile strength (UTS) ≥310 MPa (45 ksi)
Annealed 0.2% yield strength ≥210 MPa (30 ksi)
Annealed Elongation at break ≥20 %
Cold-worked Tensile strength (UTS) higher; less ductile
Elastic modulus 105 GPa

Confirm against the mill test report. C-103 retains useful strength to very high temperature; the alloy is readily formed and welded.

4. Corrosion Resistance

Environment Performance Notes
Liquid alkali metals Excellent Used in nuclear / heat-transfer service
Many acids (non-fluoride) Excellent Stable passive oxide
Atmospheric / general Good Stable at room temperature
Oxidizing atmospheres (>400 °C) Poor Oxidises in air; must be protected
High-temperature air service Coated Silicide coating (e.g. R512E) used

C-103 resists many media through a stable surface oxide, but oxidises in air at elevated temperature; for high-temperature service in air it is protected by a silicide or aluminide coating (for example R512E).

5. Heat Treatment

A refractory metal; not hardenable by precipitation. Properties are governed by working and annealing.

Anneal Anneal in vacuum or a high-purity inert atmosphere at approximately 1200–1320 °C to recrystallise and restore ductility after cold work. Avoid oxygen, nitrogen and hydrogen pickup, which embrittle the metal.

6. Weldability and Joining

Excellent weldability by inert-gas and high-vacuum processes; the weld and hot metal must be fully shielded from air, because oxygen, nitrogen and hydrogen pickup cause embrittlement.

Welding Process Applicability Notes
GTAW / TIG Excellent High-purity inert shielding or chamber
EBW (vacuum) Excellent Preferred for clean welds
Resistance / spot Good

Weld under high-purity shielding or in vacuum; protect the cooling weld from atmospheric contamination.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Machinability Soft and gummy; sharp tooling, positive rake
Tendency Galls and smears; avoid built-up edge
Coolant Ample non-chlorinated coolant

Forming Processes

Process Notes
Cold forming Excellent; very ductile when annealed
Hot forming Performed hot under protection from oxidation

8. Applications

Industry Typical Components Key Requirements
Aerospace propulsion Rocket-nozzle extensions, thrust chambers High-temperature strength + formability
Spacecraft Structures, propulsion components Strength-to-weight at temperature
Hypersonics Leading edges, hot structures Thermal shock + strength
Defense High-temperature components Refractory performance

9. Available Product Forms and Standards (ASTM System)

Product Form ASTM Standard Notes
Foil, sheet, strip and plate ASTM B654 C-103 (R04295)
Bar, rod and wire ASTM B655 C-103 (R04295)
Aerospace sheet/plate AMS 7852 C-103
Material designation UNS R04295 Nb-10Hf-1Ti

C-103 niobium-hafnium-titanium alloy (Nb-10Hf-1Ti). UNS R04295.

10. Comparison with Related Alloys (UNS System)

UNS Composition Grade Best Used For
R04200 Unalloyed Nb Type 1, reactor grade Reactor-grade niobium; nuclear service
R04210 Unalloyed Nb Type 2, commercial grade Commercial unalloyed niobium
R04251 Nb-1Zr Type 3, reactor grade Reactor-grade niobium-zirconium alloy
R04261 Nb-1Zr Type 4, commercial grade Commercial niobium-zirconium alloy
R04295 Nb-10Hf-1Ti C-103 High-temperature aerospace/propulsion alloy; rocket nozzles

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